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Application of diacetoxyiodobenzene in the desulfurization of arylthioureas

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Title Application of diacetoxyiodobenzene in the desulfurization of arylthioureas
 
Creator Singh, Sushma
Devi, Poonam
Pundeer, Rashmi
Chaudhri, Vishwas
 
Subject Diacetoxyiodobenzene
Desulfurization
Thiophilicity
Aryl thiourea
Cyanamide
 
Description 776-779
In the present study, the utility of the hypervalent iodine(III) reagent, diacetoxyiodobenzene is extended for the efficient
synthesis of variously substituted aryl cyanamides. The reaction presents efficient conversion of thioureas to cyanamides
under the conditions of ambient temperature while stirring. This organoiodine(III) mediated method features easy isolation
of the products and represents an excellent example illustrating thiophilic property of diacetoxyiodobenzene in the
desulfurization of thioureas.
 
Date 2022-07-15T10:52:54Z
2022-07-15T10:52:54Z
2022-07
 
Type Article
 
Identifier 2583-1321 (Online); 0019-5103 (Print)
http://nopr.niscpr.res.in/handle/123456789/60106
 
Language en
 
Publisher NIScPR-CSIR, India
 
Source IJC Vol.61(07) [July 2022]