Tin (IV) chloride catalysed synthesis of di(indolyl)methanes during electrophilic substitution of indoles and 2-methyl indoles
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Title |
Tin (IV) chloride catalysed synthesis of di(indolyl)methanes during electrophilic substitution of indoles and 2-methyl indoles
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Creator |
Nayak, Anupam
Banerji, Avijit Banerji, Julie |
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Subject |
Tin (IV) catalyst
ketones indole 2-methyl indole |
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Description |
697-702
An efficient methodology has been developed for the synthesis of di(indolyl)methanes in moderate to good yields during the study of the reactions of indole and 2-methyl indole using a series of aliphatic ketones in the presence of stannic chloride. It appears worth mentioning that with 2-methyl indole and acetone and ethyl methyl ketone the highly “elusive” indolylcarbinols, the postulated intermediates in the synthesis of di(indolyl)methanes, have been isolated. |
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Date |
2022-07-15T11:10:38Z
2022-07-15T11:10:38Z 2022-07 |
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Type |
Article
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Identifier |
2583-1321 (Online); 0019-5103 (Print)
http://nopr.niscpr.res.in/handle/123456789/60115 |
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Language |
en
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Publisher |
NIScPR-CSIR, India
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Source |
IJC Vol.61(07) [July 2022]
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