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Characterization of the 2-hydroxy-5-methylacetophenone and some aromatıc aldehydes condensation products by NMR and computational methods

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Title Characterization of the 2-hydroxy-5-methylacetophenone and some aromatıc aldehydes condensation products by NMR and computational methods
 
Creator Mamedov, I G
Mamedov, E I
 
Subject Ketone
aldehyde
chalcone
chromenone
NMR
molecular modeling
 
Description 961-964
A two-component Claisen-Schmidt condensation between the 2-hydoxy-5-methylacetophenone and some aromatic aldehydes has been carried out for the synthesis of chalcone derivatives at ambient temperature. The products have been obtained with good yields and as a mixture of two compounds or a single product. Piperidine has been used as a catalyst for the in situ generation of carbanion from ketone. The possibility of the formation of different products has been investigated on the based PM7 optimization, HMO theory and NMR methods.
 
Date 2022-09-19T10:17:23Z
2022-09-19T10:17:23Z
2022-09
 
Type Article
 
Identifier 2583-1321 (Online); 0019-5103 (Print)
http://nopr.niscpr.res.in/handle/123456789/60509
https://doi.org/10.56042/ijc.v61i9.66347
 
Language en
 
Publisher NIScPR-CSIR,India
 
Source IJC Vol.61(09) [Sep 2022]