<p class="ElsAuthor"><strong>PPh<sub>3</sub>-Catalyzed Intramolecular Cyclization of hydroxypropargylamides: Synthesis of Structurally Diverse Morpholinone Derivatives</strong></p>
Online Publishing @ NISCAIR
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Authentication Code |
dc |
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Title Statement |
<p class="ElsAuthor"><strong>PPh<sub>3</sub>-Catalyzed Intramolecular Cyclization of hydroxypropargylamides: Synthesis of Structurally Diverse Morpholinone Derivatives</strong></p> |
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Added Entry - Uncontrolled Name |
Paira, Moumita ; Panskura Banamali College University Grant Commision (UGC), File No. (PSW-149/14-15] |
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Uncontrolled Index Term |
Organic chemistry and heterocyclic chemistry Ugi four-component reaction (U-4CR); Post-Ugi transformations; 6-exo-dig Cyclization; Morpholinone; Hydroxypropargylamide |
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Summary, etc. |
<p>The metal-free synthesis of functionalized morpholinones through a sequential intramolecular post-ugi cyclization strategy is described. In the subsequent step, Ugi adducts hydroxypropargylamides derivative undergoes chemo- and regioselective 6-<em>exo-dig</em> catalytic cyclization to afford <em>O</em>-cyclized product in the presence of triphenylphosphine. This sequence offers an engrossing functionalized morpholinones scaffolds involving moderate reaction conditions with broad substrate scopes and moderate to good yields.</p> |
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Publication, Distribution, Etc. |
Indian Journal of Chemistry (IJC) 2022-09-20 12:49:50 |
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Electronic Location and Access |
application/pdf application/pdf http://op.niscair.res.in/index.php/IJC/article/view/59955 |
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Data Source Entry |
Indian Journal of Chemistry (IJC); ##issue.vol## 61, ##issue.no## 9 (2022): Indian Journal of Chemistry-(IJC) |
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Language Note |
en |
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Nonspecific Relationship Entry |
http://op.niscair.res.in/index.php/IJC/article/download/59955/465596122 http://op.niscair.res.in/index.php/IJC/article/download/59955/465597203 http://op.niscair.res.in/index.php/IJC/article/download/59955/465597204 |
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