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<p class="F6-SubTitle"><span>Effect of solvent change on chemical shifts of 4-benzyl-4-hydroxypiperidines</span></p><br />

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Title Statement <p class="F6-SubTitle"><span>Effect of solvent change on chemical shifts of 4-benzyl-4-hydroxypiperidines</span></p><br />
 
Added Entry - Uncontrolled Name Maruthavanan, T ; Department of Chemistry, SONASTARCH, Sona College of Technology, Salem – 636 005, Tamil Nadu, India
Manimekalai, A ; Department of Chemistry, Annamalai University, Annamalainagar – 608 002, Tamil Nadu, India
 
Uncontrolled Index Term 4-Benzyl-4-hydroxypiperidines, 1H NMR, 13C NMR, Solvent effect, Chemical shifts
 
Summary, etc. <p style="text-align: justify;">4-Benzyl-4-hydroxypiperidines <strong>1-8</strong> have been synthesized through Mannich reaction and were characterized through high resolution <sup>1</sup>H and <sup>13</sup>C NMR spectra in CDCl<sub>3</sub>.The conformational studies of the above eight compounds have been thoroughly done by using proton and <sup>13</sup>C spectral data and the assigned conformations were also supported by Hybrid HF/DFT B3LYP/6-3G* calculations. These results are published earlier by us. In order to study the effect of solvent on the chemical shifts of these piperidines, <sup>1</sup>H NMR spectra were recorded in C<sub>6</sub>D<sub>6</sub> and DMSO-<em>d</em><sub>6. </sub>The effect of change of solvents results appreciable change in the chemical shifts of various protons in the title compounds.</p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry (IJC)
2022-11-14 15:22:20
 
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http://op.niscair.res.in/index.php/IJC/article/view/68264
 
Data Source Entry Indian Journal of Chemistry (IJC); ##issue.vol## 61, ##issue.no## 11 (2022): Indian Journal of Chemistry-(IJC)
 
Language Note en