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Synthesis of 4-(benzyloxy)biphenyl under a multi-site phase-transfer catalyst along with ultrasonication – A kinetic study

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Title Synthesis of 4-(benzyloxy)biphenyl under a multi-site phase-transfer catalyst along with ultrasonication – A kinetic study
 
Creator Sathiyaraj, M
Ramya, R
Tamizharasu, G
Rajendran, V
Venkatesh, P
 
Subject Benzylchloride
Chloro-4-nitrobenzene
Interfacial reaction
MPTC
Ultrasound energy
 
Description 721-728
In this present study, the synthesis of 4-(benzyloxy)biphenyl has been successfully carried out using 4-phenylphenol and
benzyl chloride in the presence of ultrasonic power (40 kHz, 300W) along with synthesized multi - site phase - transfer
catalyst viz., N1,N2-dibenzyl-N1,N1,N2,N2-tetramethylethane-1,2-diaminium dibromide (MPTC). The pseudo first-order
kinetic equation has been applied to describe the organic reaction. The various kinetic parameters on the preparation of
4-(benzyloxy)biphenyl has been carried out under ultrasonic frequency condition and synthesized multi - site phase transfer
catalyst. Sonication has resulted in better selectivity, high yield, avoids the use of the high temperature, side products and
reduces the time consumption. The activation energy (Ea) has been calculated from the experimental results.
 
Date 2022-11-18T11:24:36Z
2022-11-18T11:24:36Z
2022-11
 
Type Article
 
Identifier 0975-0991 (Online); 0971-457X (Print)
http://nopr.niscpr.res.in/handle/123456789/60843
https://doi.org/10.56042/ijct.v29i6.67419
 
Language en
 
Publisher NIScPR-CSIR, India
 
Source IJCT Vol.29(6) [November 2022]