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<strong>Synthesis of 4-(benzyloxy)biphenyl under a multi-site phase-transfer catalyst along with ultrasonication – A kinetic study</strong>

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Title Statement <strong>Synthesis of 4-(benzyloxy)biphenyl under a multi-site phase-transfer catalyst along with ultrasonication – A kinetic study</strong>
 
Added Entry - Uncontrolled Name Sathiyaraj, M ; Department of Chemistry, Pachaiyappa’s College for Men, Kanchipuram, Tamil Nadu 631 501
Ramya, R ; Department of Chemistry, Pachaiyappa’s College for Men, Kanchipuram, Tamil Nadu 631 501
Tamizharasu, G ; Department of Chemistry, Pachaiyappa’s College for Men, Kanchipuram, Tamil Nadu 631 501
Rajendran, V ; Department of Chemistry, Pachaiyappa’s College for Men, Kanchipuram, Tamil Nadu 631 501
Venkatesh, P ; Department of Chemistry, Pachaiyappa’s College for Men, Kanchipuram, Tamil Nadu 631 501
 
Uncontrolled Index Term Benzylchloride; Chloro-4-nitrobenzene; Interfacial reaction; MPTC; Ultrasound energy
 
Summary, etc. <p><span>In this present study, the synthesis of 4-(benzyloxy)biphenyl has been successfully carried out using 4-phenylphenol and benzyl chloride in the presence of ultrasonic power (40 kHz, 300W) along with synthesized multi - site phase - transfer catalyst viz., N1,N2-dibenzyl-N1,N1,N2,N2-tetramethylethane-1,2-diaminium dibromide (MPTC). The pseudo first-order kinetic equation has been applied to describe the organic reaction. The various kinetic parameters on the preparation of 4-(benzyloxy)biphenyl has been carried out under ultrasonic frequency condition and synthesized multi - site phase transfer catalyst. Sonication has resulted in better selectivity, high yield, avoids the use of the high temperature, side products and reduces the time consumption. The activation energy (Ea) has been calculated from the experimental results.</span></p>
 
Publication, Distribution, Etc. Indian Journal of Chemical Technology (IJCT)
2022-11-22 10:22:41
 
Electronic Location and Access application/pdf
http://op.niscair.res.in/index.php/IJCT/article/view/67419
 
Data Source Entry Indian Journal of Chemical Technology (IJCT); ##issue.vol## 29, ##issue.no## 6 (2022): Indian Journal of Chemical Technology
 
Language Note en