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Title Twisted intramolecular charge transfer fluorescence in nitro-substituted alpha,omega-diphenylpolyene compounds
 
Names SINGH, AK
DARSHI, M
KANVAH, S
Date Issued 1999 (iso8601)
Abstract A fluorescence study of 1-p-cyanophenyl-4-phenylbuta-1E,3E-diene (2), 1-p-nitrophenyl-4-phenylbuta-1E,3E-diene (3), and 1-p-nitrophenyl-4-p-cyanophenylbuta-1E,3E-diene (4) in solvents of varying polarity at ambient temperature and in a 1:1 ethanol-methanol matrix at 298 and 77 K revealed that the nitro-substituted compounds are capable of exhibiting unusually red-shifted fluorescence emissions due to a twisted intramolecular charge transfer excited state.
Genre Letter
Identifier NEW JOURNAL OF CHEMISTRY,23(11)1075-1078