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Title Selenium-bridged clusters - synthesis and structural characterization of cp2mo2fe2(mu(4)-se)(mu(3)-se)2(co)6
 
Names MATHUR, P
HOSSAIN, MM
RHEINGOLD, AL
Date Issued 1993 (iso8601)
Abstract Thermolysis of Fe2(CO)6{mu-SeC(Ph)=C(H)Se} (1) and Cp2Mo2(CO)6 (2) yields the new cluster Cp2Mo2Fe2(mu4-Se)(mu3-Se)2(CO)6 (3) and Cp2Mo2(CO)4(PhCCH) (4). Structural characterization of 3 shows an unusual mu4-Se ligand bridging the two wing-tip Fe atoms and the two hinge Mo atoms of the Mo2Fe2 butterfly-tetrahedron core.
Genre Note
Identifier ORGANOMETALLICS,12(12)5029-5031