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| Field | Value |
| Title | Photochemical-reactions of alpha-methoxy-beta, gamma-enones - isolation of 1,2-acyl shift intermediate and synthesis of versatile precursors to oxygenated capnellanes |
| Names |
SINGH, V
PRATHAP, S |
| Date Issued | 1994 (iso8601) |
| Abstract | Photoreaction of strategically designed annulated bicyclo[2.2.2]octenone 8 and 9 having alpha-methoxy-beta, gamma-unsaturated carbonyl chromophore is described. The 1,2-acyl shift intermediate 11 has been isolated during irradiation of 9 and its intermediacy has been proved in the photoreaction. Synthesis of a potential precursor to oxygenated capnellanes via selective photoreaction of 8 is reported. |
| Genre | Note |
| Identifier | SYNLETT,(7)542-544 |