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A facile Michael addition reaction of β-diketones to nitrostyrenes: Alkylamino substituted triazine as an efficient organocatalyst

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Title A facile Michael addition reaction of β-diketones to nitrostyrenes: Alkylamino substituted triazine as an efficient organocatalyst
 
Creator James, Kiran
Janardhanan, Jith C
Kala, Kannankutty
Mathai, Sindhu
Manoj, Narayanapillai
 
Subject Nitro styrene
β-diketone
Organocatalyst
Michael addition
Triazine
 
Description 1316-1322
Various aminoalkyl substituted triazines have been synthesised and their activity as organocatalyst has been studied in
Michael addition reactions of β-diketones to nitrostyrenes. All the catalysts are found to be effective towards the addition
reaction and highest performance is achieved with the catalyst having long chain alkyl group. The effect of base and solvent
has also been investigated, and the condition has been optimized with triethylamine as the base and chlorobenzene as the
solvent for excellent yields. The reaction is highly remarkable since the catalyst under study is readily available and
inexpensive compared to other organocatalyst known for the reaction.
 
Date 2022-12-15T05:26:17Z
2022-12-15T05:26:17Z
2022-12
 
Type Article
 
Identifier 2583-1321 (Online); 0019-5103 (Print)
http://nopr.niscpr.res.in/handle/123456789/61011
https://doi.org/10.56042/ijc.v61i12.69447
 
Language en
 
Publisher NIScPR-CSIR,India
 
Source IJC Vol.61(12) [Dec 2022]