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Efficient conversion of aldoximes into nitriles and ketoximes into amides using bis-morpholinophosphorylchloride

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Title Efficient conversion of aldoximes into nitriles and ketoximes into amides using bis-morpholinophosphorylchloride
 
Creator Rao, P Purnachandra
Nowshuddin, Shaik
Jha, Anjali
Rao, B Leela Maheswara
Divi, Murali K
Rao, M N A
 
Subject Bis-morpholinophosphorylchloride
aldoxime
Ketoxime
Nitrile
Amide
Beckmann rearrangement
 
Description 1264-1271
Bis-morpholinophosphorylchloride (bmpc) has been identified as a new reagent to efficiently convert aldoxime into
nitriles through dehydrogenation and ketoximes into amides through Beckmann rearrangement. When compared to other
chlorophosphate reagents used earlier, which are liquids and irritating, bmpc is a non-irritating stable solid. In all the
reactions, products are obtained in high yields and purity.
 
Date 2022-12-15T06:01:20Z
2022-12-15T06:01:20Z
2022-12
 
Type Article
 
Identifier 2583-1321 (Online); 0019-5103 (Print)
http://nopr.niscpr.res.in/handle/123456789/61018
https://doi.org/10.56042/ijc.v61i12.69442
 
Language en
 
Publisher NIScPR-CSIR,India
 
Source IJC Vol.61(12) [Dec 2022]