Efficient conversion of aldoximes into nitriles and ketoximes into amides using bis-morpholinophosphorylchloride
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Title |
Efficient conversion of aldoximes into nitriles and ketoximes into amides using bis-morpholinophosphorylchloride
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Creator |
Rao, P Purnachandra
Nowshuddin, Shaik Jha, Anjali Rao, B Leela Maheswara Divi, Murali K Rao, M N A |
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Subject |
Bis-morpholinophosphorylchloride
aldoxime Ketoxime Nitrile Amide Beckmann rearrangement |
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Description |
1264-1271
Bis-morpholinophosphorylchloride (bmpc) has been identified as a new reagent to efficiently convert aldoxime into nitriles through dehydrogenation and ketoximes into amides through Beckmann rearrangement. When compared to other chlorophosphate reagents used earlier, which are liquids and irritating, bmpc is a non-irritating stable solid. In all the reactions, products are obtained in high yields and purity. |
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Date |
2022-12-15T06:01:20Z
2022-12-15T06:01:20Z 2022-12 |
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Type |
Article
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Identifier |
2583-1321 (Online); 0019-5103 (Print)
http://nopr.niscpr.res.in/handle/123456789/61018 https://doi.org/10.56042/ijc.v61i12.69442 |
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Language |
en
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Publisher |
NIScPR-CSIR,India
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Source |
IJC Vol.61(12) [Dec 2022]
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