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Optimization of gas chromatography-single quadrupole mass spectrometry conditions for multiresidue analysis of pesticides in grapes in compliance to EU-MRLs.

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Title Optimization of gas chromatography-single quadrupole mass spectrometry conditions for multiresidue analysis of pesticides in grapes in compliance to EU-MRLs.
Not Available
 
Creator Banerjee Kaushik, Mujawar S., Utture S. Dasgupta S., Adsule P.G.
 
Subject Multiresidue analysis of pesticides in grapes
GC-MS
Analytical method validation
 
Description Not Available
A single quadrupole GC–MS method was optimized for multiresidue determination of 47 pesticides in grapes with limit of quantifications of each compound in compliance with the EU-MRL requirements. Sample preparation involved extraction of 10 g sample with 10 ml ethyl acetate ( + 10 g sodium sulphate) by homogenization at 15,000 rpm followed by centrifugation at 3000 rpm. The supernatant was cleaned by dispersive solid phase extraction with primary secondary amine and acidified with 0.1% formic acid. Residues were estimated in selected ion monitoring mode with programmable temperature vaporizer-large volume injection (8 μl). All the GC and MS parameters were thoroughly optimized to achieve satisfactory linearity (R2 > 0.99) within 0.01–0.25 mg kg−1 with minimum matrix interferences. Recoveries at 0.01 and 0.02 mg kg−1 were within 67–120% with associated precision RSD below 19%. The method was successfully applied for analysis of the real world samples for incurred residues.
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Date 2021-04-14T08:41:02Z
2021-04-14T08:41:02Z
2013-05-01
 
Type Journal
 
Identifier Banerjee Kaushik, Mujawar S., Utture S. Dasgupta S., Adsule P.G. (2013). Optimization of gas chromatography-single quadrupole mass spectrometry conditions for multiresidue analysis of pesticides in grapes in compliance to EU-MRLs. Food Chemistry 138: 600-607
https://doi.org/10.1016/j.foodchem.2012.10.105
http://krishi.icar.gov.in/jspui/handle/123456789/46468
 
Language English
 
Relation Not Available;
 
Publisher Elsevier