Record Details

Improved chromatographic performance in red chilli powder pesticide residue quantitation by retention gap introduction in gas chromatography tandem mass spectrometry

KRISHI: Publication and Data Inventory Repository

View Archive Info
 
 
Field Value
 
Title Improved chromatographic performance in red chilli powder pesticide residue quantitation by retention gap introduction in gas chromatography tandem mass spectrometry
Not Available
 
Creator Chandrasekar Kandaswamy
Davis Presley
Ahammed Shabeer TP
Sreekanth Anadaram
 
Subject QuEChERS
Multiresidue pesticides
Red chilli
GC–MS/MS Optimization
Retention gap
Spices
 
Description Not Available
Analysis of agrochemical residues in red chilli powder is always considered difficult because of higher matrix interference due to carotenoid pigments and other co-extractives. During the sample preparation, matrix components were co-extracted along with the target compounds leading to frequent source cleaning, changing of liner and column. Efforts were made to improve the chromatographic performance by optimizing sample preparation, choosing matrix-free transitions and introducing a retention gap. The Quick, Easy, Cheap, Effective, Rugged and Safe (QuEChERS) extraction was experimented using different dispersive adsorbents and the purified extract was analyzed by gas chromatography tandem mass spectrometry (GC–MS/MS) system. 84 pesticides under different class were validated and established a limit of quantification of 0.002–0.007 mgkg−1. The recovery was between 70 and 110% at 0.01, 0.025 and 0.05 mgkg−1 fortification level and corresponding precision was between 3 and 16% RSD. Suitability of the validated method was established through analysis of market samples of chilli powder for the quantitation of targeted pesticide residues.
Not Available
 
Date 2021-07-27T04:33:48Z
2021-07-27T04:33:48Z
2021-07-05
 
Type Article
 
Identifier Kandaswamy, C., Presley, D., Ahammed, T.P.S. et al. Improved chromatographic performance in red chilli powder pesticide residue quantitation by retention gap introduction in gas chromatography tandem mass spectrometry. J Food Sci Technol (2021). https://doi.org/10.1007/s13197-021-05177-3
Not Available
http://krishi.icar.gov.in/jspui/handle/123456789/50217
 
Language English
 
Relation Not Available;
 
Publisher Springer