<p>Efficient conversion of aldoximes into nitriles and ketoximes into amides using bis-morpholinophosphorylchloride<strong></strong></p>
Online Publishing @ NISCAIR
View Archive InfoField | Value | |
Authentication Code |
dc |
|
Title Statement |
<p>Efficient conversion of aldoximes into nitriles and ketoximes into amides using bis-morpholinophosphorylchloride<strong></strong></p> |
|
Added Entry - Uncontrolled Name |
Rao, P Purnachandra; Divis Research Center, Divis Laboratories Limited, B-34, Industrial Estate, Sanathnagar, Hyderabad, Telangana-500 018, India Nowshuddin, Shaik ; Divis Research Center, Divis Laboratories Limited, B-34, Industrial Estate, Sanathnagar, Hyderabad, Telangana-500 018, India Jha, Anjali ; Department of Chemistry, GIS, GITAM (Deemed to be University), Visakhapatnam, Andhra Pradesh-530 045, India Rao, B Leela Maheswara; Divis Research Center, Divis Laboratories Limited, B-34, Industrial Estate, Sanathnagar, Hyderabad, Telangana-500 018, India Divi, Murali K; Divis Research Center, Divis Laboratories Limited, B-34, Industrial Estate, Sanathnagar, Hyderabad, Telangana-500 018, India Rao, M N A; Divis Research Center, Divis Laboratories Limited, B-34, Industrial Estate, Sanathnagar, Hyderabad, Telangana-500 018, India |
|
Uncontrolled Index Term |
Bis-morpholinophosphorylchloride, aldoxime, Ketoxime, Nitrile, Amide, Beckmann rearrangement. |
|
Summary, etc. |
<p style="text-align: justify;">Bis-morpholinophosphorylchloride(bmpc) has been identified as a new reagent to efficiently convert aldoxime into nitriles through dehydrogenation and ketoximes into amides through Beckmann rearrangement. When compared to other chlorophosphate reagents used earlier, which are liquids and irritating, bmpc is a non-irritating stable solid. In all the reactions, products are obtained in high yields and purity.</p> |
|
Publication, Distribution, Etc. |
Indian Journal of Chemistry (IJC) 2022-12-19 17:29:37 |
|
Electronic Location and Access |
application/pdf application/pdf http://op.niscair.res.in/index.php/IJC/article/view/69442 |
|
Data Source Entry |
Indian Journal of Chemistry (IJC); ##issue.vol## 61, ##issue.no## 12 (2022): Indian Journal of Chemistry-(IJC) |
|
Language Note |
en |
|