ICAR Research Data Repository for Knowledge Management
A Synergic Blend of Newly Isolated Pseudomonas mandelii KJLPB5 and [hmim]Br for Chemoselective 2 Aryl Alcohol Oxidation in H2O2: Synthesis of Aryl Ketone or Aldehydes via Sequential Dehydration-Oxidative C=C Cleavage
KRISHI: Publication and Data Inventory Repository
View Archive Info| Field | Value | |
| Title |
A Synergic Blend of Newly Isolated Pseudomonas mandelii KJLPB5 and [hmim]Br for Chemoselective 2 Aryl Alcohol Oxidation in H2O2: Synthesis of Aryl Ketone or Aldehydes via Sequential Dehydration-Oxidative C=C Cleavage
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| Creator |
Nandini Sharma
Upendra K. Sharma Richa Salwan Ramesh C. Kasana Arun K. Sinha |
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| Subject |
Biocatalysis, Pseudomonas mandelii, Ionic liquid, Alkene cleavage, Oxidation
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| Description |
Not Available
Pseudomonas mandelii KJLPB5 is reported for the oxidation of aryl alcohols in ionic liquid [hmim]Br (1-hexyl-3-methyl imidazolium bromide) with H2O2. With a slight alteration of reaction conditions, the developed protocol leads either to (i) chemoselective oxidation of 2 aryl alcohols over 1 and aliphatic counterparts or (ii) direct one pot-two step sequential conversion of 2 aryl alcohols into corresponding one or two carbons shorter aryl aldehydes through oxidative cleavage pathway, thus providing a new facet to metal-free oxidations. The key operational parameters such as substrate concentration, incubation temperature, incubation time, ionic liquid type and ionic liquid concentration are also optimized. Not Available |
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| Date |
2019-05-02T04:37:32Z
2019-05-02T04:37:32Z 2011-01-05 |
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| Type |
Research Paper
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| Identifier |
6
Not Available http://krishi.icar.gov.in/jspui/handle/123456789/19113 |
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| Language |
English
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| Relation |
Not Available;
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| Publisher |
Springer
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