Crystal structure of dimethyl ammonium 5-(2,4-dinitrophenyl)-1,3-dimethyl barbiturate
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Title |
Crystal structure of dimethyl ammonium 5-(2,4-dinitrophenyl)-1,3-dimethyl barbiturate
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Creator |
Bhavya, M
Malarvizhi, R |
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Subject |
N,N-Dimethyl amine
1-chloro-2,4-dinitrobenzene 1,3-dimethylbarbituric acid NMR spectral analysis Single crystal diffraction |
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Description |
65-71
The titled molecular salt dimethyl ammonium 5-(2,4-dinitrophenyl)-1,3-dimethyl barbiturate has been prepared from the ethanolic solution of 1-chloro-2,4-dinitrobenzene, 1,3-dimethylbarbituric acid and dimethyl amine. FT-IR, 1H-NMR, 13CNMR, and single crystal diffraction results support the proposed structure of the compound. The crystal structure of the titled complex [monoclinic, space group p21/n, a=11.5729 (15)Å, b=8.6857(11) Å, c=16.701(2) Å, Z=4] are analyzed by single-crystal X-ray diffraction. In this crystal, intermolecular N-H…O and C-H…O hydrogen bonds forming a three dimensional network and small red spot in Hirshfeld surfaces indicates the presence of C-H...π interactions. |
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Date |
2023-01-18T10:31:39Z
2023-01-18T10:31:39Z 2023-01 |
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Type |
Article
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Identifier |
2583-1321 (Online); 0019-5103 (Print)
http://nopr.niscpr.res.in/handle/123456789/61212 https://doi.org/10.56042/ijc.v62i1.70396 |
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Language |
en
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Publisher |
NIScPR-CSIR,India
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Source |
IJC Vol.62(01) [Jan 2023]
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