ICAR Research Data Repository for Knowledge Management
Novel reactions and mechanism of -HN-N= azole derivatives with DMSO
Online Publishing @ NISCAIR
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| Authentication Code |
dc |
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| Title Statement |
Novel reactions and mechanism of -HN-N= azole derivatives with DMSO |
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| Added Entry - Uncontrolled Name |
Dong, Hong-Ru ; School of Chemical Engineering, Lanzhou University of Arts and Science, Lanzhou 730000, Gansu, P.R. China |
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| Uncontrolled Index Term |
Reaction mechanism, –NH-N= azole derivatives, Sulfur ketones derivatives, (Methylthio)methyl-triazole, Free-mediated, Pummerer rearrangement |
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| Summary, etc. |
<p style="text-align: justify;">The reaction mechanism of –NH-N= azole derivatives and sulfur ketones derivatives is reported. The reaction mechanism is suitable for the synthesis of azole compounds containing thio-function. The free-mediated reaction mechanism of –NH-N= azole and DMSO is not agree with Pummerer rearrangement reaction. Some new ethyl 5-(arylamino)-2-[(methylthio)methyl]-2<em>H</em>-1,2,3-triazole-4-carboxylate <strong>6a-j</strong> have been synthesized by 5-amino-1-aryl-1,2,3-triazol-4-caroxylic acid ethyl ester <strong>4a-j</strong> and DMSO. The new compounds have been characterized by <sup>1</sup>H NMR, MS, IR, HRMS and single-crystal X-ray diffraction.</p> |
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| Publication, Distribution, Etc. |
Indian Journal of Chemistry (IJC) 2023-01-19 15:48:46 |
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| Electronic Location and Access |
application/pdf application/pdf http://op.niscair.res.in/index.php/IJC/article/view/70393 |
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| Data Source Entry |
Indian Journal of Chemistry (IJC); ##issue.vol## 62, ##issue.no## 1 (2023): Indian Journal of Chemistry-(IJC) |
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| Language Note |
en |
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