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<p><strong>Functionalization of fullerene with 4-benzo-9-crown-3 ether</strong></p>

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Title Statement <p><strong>Functionalization of fullerene with 4-benzo-9-crown-3 ether</strong></p>
 
Added Entry - Uncontrolled Name kiani, maryam
 
Uncontrolled Index Term Covalent grafting; Crown ether; Fullerene; Functionalization; Phase transfer catalyst
 
Summary, etc. <span>Functionalization of fullerene via covalent addition of substituted 4-benzo-9-crown-3 ether diazonium salt has been described. This procedure is used for the preparation of new derivative fullerenes which is described as a phase transfer catalyst. The covalent grafting has led to a considerable increment in the solubility of fullerene in organic solvents such as, CH2Cl2, acetone and ethanol. The covalent grafting of crown ether (4-(benzo-9-crown-3)) to fullerene (Fullerene-CE) has been identified and confirmed by IR, H-NMR, 7Li-NMR and thermogravimetric analysis (TGA) methods. Fullerene-CE in solvents has been used as a phase transfer catalyst for organic reactions. The Fullerene-CE is capable to become the Li+ host.</span>
 
Publication, Distribution, Etc. Indian Journal of Chemical Technology (IJCT)
2023-01-30 15:34:14
 
Electronic Location and Access application/pdf
http://op.niscair.res.in/index.php/IJCT/article/view/64953
 
Data Source Entry Indian Journal of Chemical Technology (IJCT); ##issue.vol## 30, ##issue.no## 1 (2023): Indian Journal of Chemical Technology
 
Language Note en