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Synthesis of linear cis-anti-cis triquinane derivative via a [3+2] cycloaddition and Krapcho decarboxylation as key steps
NOPR - NISCAIR Online Periodicals Repository
View Archive Info| Field | Value | |
| Title |
Synthesis of linear cis-anti-cis triquinane derivative via a [3+2] cycloaddition and Krapcho decarboxylation as key steps
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| Creator |
Kotha, Sambasivarao
Agrawal, Arpit |
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| Subject |
Triquinane
Cycloaddition Decarboxylation Oxidative Cleavage Cyclopentane |
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| Description |
527-531
A short synthetic sequence to a linear triquinane is reported involving [3+2] cycloaddition, oxidative cleavage of double bond using ruthenium catalyst followed by decarboxylation. By this methodology, norbornene double bond can be easily cleaved to obtain the linear triquinane unit. This methodology is useful for the synthesis of natural and non-natural products having fused cyclopentane ring systems. |
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| Date |
2023-05-18T05:09:52Z
2023-05-18T05:09:52Z 2023-05 |
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| Type |
Article
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| Identifier |
2583-1321 (Online); 0019-5103 (Print)
http://nopr.niscpr.res.in/handle/123456789/61921 https://doi.org/10.56042/ijc.v62i5.1433 |
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| Language |
en
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| Publisher |
NIScPR-CSIR,India
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| Source |
IJC Vol.62(05) [May 2023]
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