Synthesis of new complex [Bi6O6(OH)2](ClC6H4SO3)4 and investigation of its thermal decomposition
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Title |
Synthesis of new complex [Bi6O6(OH)2](ClC6H4SO3)4 and investigation of its thermal decomposition
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Creator |
Kaloyanov, Nikolay
Zahariev, Alexander Parvanova, Veneta Avdeev, Georgi Girginov, Christian |
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Subject |
Bi(III) complexes
Thermal decomposition TG-DTA XRD FTIR |
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Description |
431-436
A new [Bi6O6(OH)2](ClC6H4SO3)4 complex is synthesized through a reaction of Bi2O3 with aqueous 4-chlorobenzenesulfonic acid at elevated temperature. The product composition is elucidated by elemental analysis, ICP-OES and FTIR techniques. By means of XRD analysis, the compound’s indexation, monoclinic P2(3) space group and unit cell parameters: a=31.25(3) Å, b=19.78(1) Å, c=8.795(8) Å, γ = 94.33(4)o as well as a cell volume = 5424.21 Å3 are determined. Based on DTA-TG technique, three specific temperatures aimed at studying product’s thermal decomposition are determined. The compositions of solid residues after isothermal heating are proved following the XRD and FTIR data. |
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Date |
2023-05-18T05:35:59Z
2023-05-18T05:35:59Z 2023-05 |
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Type |
Article
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Identifier |
2583-1321 (Online); 0019-5103 (Print)
http://nopr.niscpr.res.in/handle/123456789/61931 https://doi.org/10.56042/ijc.v62i5.1434 |
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Language |
en
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Publisher |
NIScPR-CSIR,India
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Source |
IJC Vol.62(05) [May 2023]
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