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Kinetics and mechanism of oxidation of cinnamyl alcohol by N-chloro p-toluene sulphonamide (Chloramine-T) in acid perchlorate medium
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View Archive Info| Field | Value | |
| Title |
Kinetics and mechanism of oxidation of cinnamyl alcohol by N-chloro p-toluene sulphonamide (Chloramine-T) in acid perchlorate medium
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| Creator |
Meena, Anita
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| Subject |
Kinetics, Mechanism
Oxidation Cinnamyl Alcohol Chloramine-T |
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| Description |
803-807
The kinetics of oxidation of cinnamyl alcohol by N-chloro-p-toluene sulphonamide (Chloramine-T) in an aqueous acid medium has been studied. The reaction is first order with respect to the oxidant but exhibits rate independence of substrate concentration. Rate is retarded by hydrogen ion concentration due to protonation of Chloramine-T. The product toluene-psulphonamide does not affect the rate of reaction. The cinnamyl aldehyde has been observed to be the oxidation product spectrally. |
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| Date |
2023-08-16T13:02:58Z
2023-08-16T13:02:58Z 2023-08 |
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| Type |
Article
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| Identifier |
2583-1321 (Online); 0019-5103 (Print)
http://nopr.niscpr.res.in/handle/123456789/62459 https://doi.org/10.56042/ijc.v62i8.87 |
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| Language |
en
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| Publisher |
NIScPR-CSIR, India
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| Source |
IJC Vol.62(08) [August 2023]
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