Record Details

Electrochemical conversion of benzene sulphonyl azide into sulphonamide assisted by sodium ascorbate

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Field Value
 
Title Electrochemical conversion of benzene sulphonyl azide into sulphonamide assisted by sodium ascorbate
 
Creator Deena, Paliakkara Lona
Selvaraj, Savariraj Joseph
 
Subject Sulphonyl azide
Electrochemical reduction
Sodium ascorbate
Cyclic voltammetry
 
Description 980-985
Chemical reduction of organic azides is a commonly accepted route in synthetic organic chemistry to prepare amino compounds. Researchers and scientists are interested in choosing greener pathways in the course of the synthesis of organic molecules. In the present work we report the synthesis of benzene sulphonamide by the electrochemical reduction of benzene sulphonyl azide using platinum electrodes. Influence of current density and voltage, effect of electrolytes, effect of solvents and effect of substrate concentration on the yield of the product have been studied. The reaction is more feasible in the presence of sodium ascorbate (in 1:1 methanol-water) which acts as both supporting electrolyte and electron transferring agent in the electrochemical process.
 
Date 2023-09-19T04:59:15Z
2023-09-19T04:59:15Z
2023-09
 
Type Article
 
Identifier 2583-1321 (Online); 0019-5103 (Print)
http://nopr.niscpr.res.in/handle/123456789/62511
https://doi.org/10.56042/ijc.v62i9.5381
 
Language en
 
Publisher NIScPR-CSIR,India
 
Source IJC Vol.62(09) [September 2023]