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Ru(III) catalysed oxidation of EDTA by N-bromophthaliamide in aqueous alkaline medium: A kinetic and mechanistic study

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Title Ru(III) catalysed oxidation of EDTA by N-bromophthaliamide in aqueous alkaline medium: A kinetic and mechanistic study
 
Creator S, Shailashree
Mukhjerjee, Suvodip
Surekha, M
 
Subject NBP
EDTA
Oxidation
Kinetics
Alkaline medium
 
Description 245-252
The present study discusses the NBP oxidation in alkaline medium. Different workers have acknowledged unexpected
products with unusual oxidants for EDTA oxidation. The role of the homogeneous catalyst ruthenium(III) has been
investigated in alkaline media. It forms various intermediate complexes, oxidation states and free radicals. Herein, we have
given an account of the Ru(III) catalyzed oxidation of EDTA by NBP to elucidate the possible mechanism and immediate
species of oxidant, reductant and catalyst.
 
Date 2024-03-19T11:18:29Z
2024-03-19T11:18:29Z
2024-03
 
Type Article
 
Identifier 2583-1321 (Online); 0019-5103 (Print)
http://nopr.niscpr.res.in/handle/123456789/63598
https://doi.org/10.56042/ijc.v63i3.2562
 
Language en
 
Publisher NIScPR-CSIR,India
 
Source IJC Vol.63(03) [March 2024]