ICAR Research Data Repository for Knowledge Management
Wacker oxidation with 2,5-diallyl PCUD derivatives
NOPR - NISCAIR Online Periodicals Repository
View Archive Info| Field | Value | |
| Title |
Wacker oxidation with 2,5-diallyl PCUD derivatives
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| Creator |
Kotha, Sambasivarao
Chaurasia, Usha Nandan Gaikwad, Vidyasagar |
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| Subject |
Claisen rearrangement
Dehydration Luche reduction PCUD Wacker oxidation |
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| Description |
727-731
Herein is reported a simple synthetic approach to functionalized polycyclic cage compounds related to Cookson’s dione derivative by utilizing Claisen rearrangement, Diels−Alder reaction (DA), [2+2] photocycloaddition, Luche reduction, dehydration, and Wacker oxidation as key steps. Access to such hybrid molecules containing heterocycles and caged systems provides new opportunities in medicinal chemistry and access to high energy density materials (HEDMs). 2,5-Diallyl cage compounds containing diallyl moiety have been successfully functionalized into methyl ketones by Wacker oxidation. |
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| Date |
2024-07-19T06:35:00Z
2024-07-19T06:35:00Z 2024-07 |
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| Type |
Article
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| Identifier |
2583-1321 (Online); 0019-5103 (Print)
http://nopr.niscpr.res.in/handle/123456789/64256 https://doi.org/10.56042/ijc.v63i7.11398 |
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| Language |
en
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| Publisher |
NIScPR-CSIR,India
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| Source |
IJC Vol.63(07) [July 2024]
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