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Electrocatalytic Performance of NiSe Nanoparticles Doped ZIF-67 Derived Electrocatalyst for Hydrogen Evolution Reaction

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Title Electrocatalytic Performance of NiSe Nanoparticles Doped ZIF-67 Derived Electrocatalyst for Hydrogen Evolution Reaction
 
Creator Mane, Rupali S
Marar, Balgopal
Jha, Neetu
 
Subject ZIF 67
Over-potential
Tafel-slope
Electrochemical Active Surface Area (ECSA)
 
Description 712-717
Herein we report an electrocatalyst for hydrogen evolution reaction (HER) by using cobalt-based zeolite imidazolate
framework (ZIF67) as a synthesized precursor, along with its composites using Ni and Se nanoparticles. The morphology
and structure of the samples were studied by using FESEM analysis, XRD diffraction method, IR spectra, and BET analysis.
The final composite with Ni and Se doped ZIF 67 shows an over potential of 114 mV at a current density of 10 mA cm-2 and
a Tafel slope of 46 mV dec-1 compared to that of commercial Pt/C catalyst. The metal-metal interaction on the ZIF 67 frame
work were found to serve as an active site. The co-doping producing a synergetic effect helps in enhancing the activity of
the optimized catalyst.
 
Date 2024-08-05T10:10:22Z
2024-08-05T10:10:22Z
2024-08
 
Type Article
 
Identifier 0975-0959 (Online); 0301-1208 (Print)
http://nopr.niscpr.res.in/handle/123456789/64322
https://doi.org/10.56042/ijpap.v62i8.7467
 
Language en
 
Publisher NIScPR-CSIR,India
 
Source IJPAP Vol.62(08) [August 2024]